Effect of copper-enriched layers on localized corrosion of aluminium-copper alloys
Article Sidebar
PDF
XML
Published
May 15, 2018
Section: PAPERS
How to Cite
Arenas-Vara, M., Skeldon, P., & García-Vergara, S. (2018). Effect of copper-enriched layers on localized corrosion of aluminium-copper alloys. Revista Facultad De Ingeniería, 27(48), 7-15. https://doi.org/10.19053/01211129.v27.n48.2018.8016
More Citation Formats
Main Article Content
Autores
María Ángeles Arenas-VaraPeter Skeldon
Sandra Judith García-Vergara
Abstract
Copper-enriched layers were developed onto aluminum-copper alloys using alkaline etching in sodium hydroxide, for both, sputter deposited and bulk conditions. Enriched alloys were evaluated by potentiodynamic polarization in sodium chloride solution in order to determine the effect of the enriched layers on the pitting potential of the alloys. Rutherford backscattering spectroscopy was employed to quantify the enrichments and their locations just beneath the alumina-based oxides remaining from the etching. For the sputter deposited aluminum-copper alloys, the results show some scattering of the pitting potential data, and no correlation between pitting potential and the alloy enriched layer. In the case of bulk Al-2wt.%Cu alloy, with the copper in solid-solution, the pitting potential increased for the enriched specimens, indicating also a different pit morphology, with respect to the non-enriched alloy.
Article Details
Licence
This work is licensed under a Creative Commons Attribution 4.0 International License.
The journal authorizes the total or partial reproduction of the published article, as long as the source, including the name of the Journal, author(s), year, volume, issue, and pages are cited.
The ideas and assertions expressed by the authors are their solely responsibility and do not represent the views and opinions of the Journal or its editors.
All articles included in the Revista Facultad de Ingeniería are published under the Creative Commons (BY) license.
Authors must complete, sign, and submit the Review and Publication Authorization Form of the manuscript provided by the Journal; this form should contain all the originality and copyright information of the manuscript.
The authors keep copyright, however, once the work in the Journal has been published, the authors must always allude to it.
References
[1] M. K. Cavanaugha, J.-C. Lia, N. Birbilis, and R. G. Buchheit, “Electrochemical Characterization of Intermetallic Phases Common to Aluminum Alloys as a Function of Solution Temperature,” J. Electrochem. Soc., vol. 161, pp. C535-C543, Dec. 2014. DOI: http://doi.org/10.1149/2.0361412jes.
[2] N. Birbilis, and R. G. Buchheit, “Electrochemical Characteristics of Intermetallic Phases in Aluminum Alloys,” J. Electrochem. Soc., vol. 152, pp. B140-B151, Apr. 2015. DOI: http://doi.org/10.1149/1.1869984.
[3] H. H. Strehblow, and C. J. Doherty, “Examination of aluminum copper films during anodic oxidation,” J. Electrochem. Soc., vol. 125, pp. 30–33, Jan. 1978. DOI: http://doi.org/10.1149/1.2131392.
[4] M. A. Paez, T. M. Foong, C.T. Ni, G.E. Thompson, K. Shimizu, H. Habazaki, P. Skeldon, and G.C. Wood, “Barrier-type anodic film formation on an Al-3.5 wt% Cu alloy,” Corros. Sci., vol. 38 (1), pp. 59-72, Jan.1996.
[5] X. Zhou, H. Habazaki, K. Shimizu, P. Skeldon, G.E. Thompson, and G.C. Wood, “Copper enrichment in Al–Cu alloys due to electropolishing and anodic oxidation,” Thin Solid Films, vol. 293 (1-2), pp. 327–332, Jan. 1997. DOI: http://doi.org/10.1016/S0040-6090(96)09117-1.
[6] Y. Liu, E. A. Sultan, E. V. Koroleva, P. Skeldon, G. E. Thompson, X. Zhou, K. Shimizu, and H. Habazaki, “Grain orientation effects on copper enrichment and oxygen generation during anodizing of an Al-1 at.% Cu alloy,” Corros. Sci., vol 45(4), pp. 789–797, Apr. 2003. DOI: http://doi.org/10.1016/S0010-938X(02)00126-9.
[7] Y. Ma, X. Zhou, G. E. Thompson, M. Curioni, T. Hashimoto, P. Skeldon, P. Thomson, and M. Fowles, “Anodic film formation on AA 2099-T8 aluminium alloy in tartaric-sulphuric acid,” J. Electrochem. Soc., vol. 158 (2), pp. C17–C22, Feb. 2011. DOI: http://doi.org/10.1149/1.3523262.
[8] R. K. Gupta, N. L. Sukiman, M. K. Cavanaugh, B. R. W. Hinton, C. R. Hutchinson, and N. Birbilis, “Metastable pitting characteristics of aluminium alloys measured using current transients during potentiostatic polarization,” Electrochim. Acta, vol. 66, pp. 245–254. Apr. 2012. DOI: http://doi.org/10.1016/j.electacta.2012.01.090.
[9] J. Pierrière, “Rutherford backscattering spectrometry,” Vacuum, vol. 37 (5-6), pp. 429-432, May. 1987. DOI: http://doi.org/10.1016/0042-207X(87)90327-7.
[10] L. R. Doolittle, “Algorithms for the rapid simulation of Rutherford backscattering spectra,” Nucl. Instrum. Meth.B, vol. 9(1), pp. 344-351, Jun. 1985. DOI: http://doi.org/10.1016/0168-583X(85)90762-1.
[11] G. S. Frankel, J. R. Scully, and C. V. Jahnes, “Repassivation of Pits in Aluminum Thin Films,” J. Electrochem. Soc., vol. 143 (6), pp. 1834-1840, Jun. 1996. DOI: http://doi.org/10.1149/1.1836912.
[12] J. R. Galvele, “Transport processes in passivity breakdown—II. Full hydrolysis of the metal ions,” Corros. Sci., vol. 21 (8), pp. 551-579, Aug. 1981. DOI: http://doi.org/10.1016/0010-938X(81)90009-3.
[13] S. Garcia-Vergara, F. Colin, P. Skeldon, G. E. Thompson, P. Bailey, T. C. Q. Noakes, H. Habazaki, and K. Shimizu, “Effect of Copper Enrichment on the Electrochemical Potential of Binary Al-Cu Alloys,” J. Electrochem. Soc., vol. 151 (1), pp. B16-B21, Jan. 2004. DOI: http://doi.org/10.1149/1.1627343.
[14] A. Broli, and H. Holtan, “Use of potentiokinetic methods for the determination of characteristic potentials for pitting corrosion of aluminium in a deaerated solution of 3%NaCl,” Corros. Sci., vol. 13(4), pp. 237-246, Apr. 1973. DOI: http://doi.org/10.1016/0010-938X(73)90002-4.
[15] G. S. Frankel, “The growth of 2-D pits in thin film aluminium,” Corros. Sci., vol. 30 (12), pp. 1203-1218, Dec. 1990. DOI: http://doi.org/10.1016/0010-938X(90)90199-F.
[16] G. S. Frankel, M. A. Russak, C. V. Jahnes, M. Mirzamaani, and V. A. Brusic, “Pitting of Sputtered Aluminum Alloy Thin Films,” J. Electrochem. Soc., vol. 136(4), pp.1243-1244, Apr. 1989. DOI: http://doi.org/10.1149/1.2096864.
[17] X. Zhou, H. Habazaki, K. Shimizu, P. Skeldon, G. E. Thompson, and G. C. Wood, “Enrichment-dependent anodic oxidation of Zinc in Al-Zn Alloys,” Corros. Sci., vol. 38 (9), pp. 1563-1577, Sep. 1996.
[18] G. D. Davis, B. A. Shaw, B. J. Rees, and C. A. Pecile, “Electrochemical behavior and surface chemistry of non‐equilibrium aluminum–tantalum alloys: Solute‐rich interphase mechanisms,” Surf. Int. Anal., vol. 23 (9), pp. 609-617, Aug. 1995. DOI: http://doi.org/10.1002/sia.740230906.
[19] G. S. Frankel, R. C. Newman, C. V. Jahnes, and M. A. Russak, “On the Pitting Resistance of Sputter‐Deposited Aluminum Alloys,” J. Electrochem. Soc., vol. 140 (8), pp. 2192-2197, Aug. 1993. DOI: http://doi.org/10.1149/1.2220794.
[20] M. M. Lohrengel, “Thin anodic oxide layers on aluminium and other valve metals: high field regime,” Mat. Sci. Eng. R, vol. 11(6), pp. 243-294, Dec. 1993. DOI: http://doi.org/10.1016/0927-796X(93)90005-N.
[21] X. Zhou, C. Luo, T. Hashimoto, A.E. Hughes, and G.E. Thompson, “Study of localized corrosion in AA2024 aluminium alloy using electron tomography,” Corros. Sci., vol. 58, pp. 299-306, May. 2012. DOI: http://doi.org/10.1016/j.corsci.2012.02.001.
[22] X. Zhang, X. Zhou, T. Hashimoto, and B. Liu, “Localized corrosion in AA2024-T351 aluminium alloy: Transition from intergranular corrosion to crystallographic pitting,” Mat. Characterization, vol. 130, pp. 230-236, Aug. 2017. DOI: http://doi.org/10.1016/j.matchar.2017.06.022.
[2] N. Birbilis, and R. G. Buchheit, “Electrochemical Characteristics of Intermetallic Phases in Aluminum Alloys,” J. Electrochem. Soc., vol. 152, pp. B140-B151, Apr. 2015. DOI: http://doi.org/10.1149/1.1869984.
[3] H. H. Strehblow, and C. J. Doherty, “Examination of aluminum copper films during anodic oxidation,” J. Electrochem. Soc., vol. 125, pp. 30–33, Jan. 1978. DOI: http://doi.org/10.1149/1.2131392.
[4] M. A. Paez, T. M. Foong, C.T. Ni, G.E. Thompson, K. Shimizu, H. Habazaki, P. Skeldon, and G.C. Wood, “Barrier-type anodic film formation on an Al-3.5 wt% Cu alloy,” Corros. Sci., vol. 38 (1), pp. 59-72, Jan.1996.
[5] X. Zhou, H. Habazaki, K. Shimizu, P. Skeldon, G.E. Thompson, and G.C. Wood, “Copper enrichment in Al–Cu alloys due to electropolishing and anodic oxidation,” Thin Solid Films, vol. 293 (1-2), pp. 327–332, Jan. 1997. DOI: http://doi.org/10.1016/S0040-6090(96)09117-1.
[6] Y. Liu, E. A. Sultan, E. V. Koroleva, P. Skeldon, G. E. Thompson, X. Zhou, K. Shimizu, and H. Habazaki, “Grain orientation effects on copper enrichment and oxygen generation during anodizing of an Al-1 at.% Cu alloy,” Corros. Sci., vol 45(4), pp. 789–797, Apr. 2003. DOI: http://doi.org/10.1016/S0010-938X(02)00126-9.
[7] Y. Ma, X. Zhou, G. E. Thompson, M. Curioni, T. Hashimoto, P. Skeldon, P. Thomson, and M. Fowles, “Anodic film formation on AA 2099-T8 aluminium alloy in tartaric-sulphuric acid,” J. Electrochem. Soc., vol. 158 (2), pp. C17–C22, Feb. 2011. DOI: http://doi.org/10.1149/1.3523262.
[8] R. K. Gupta, N. L. Sukiman, M. K. Cavanaugh, B. R. W. Hinton, C. R. Hutchinson, and N. Birbilis, “Metastable pitting characteristics of aluminium alloys measured using current transients during potentiostatic polarization,” Electrochim. Acta, vol. 66, pp. 245–254. Apr. 2012. DOI: http://doi.org/10.1016/j.electacta.2012.01.090.
[9] J. Pierrière, “Rutherford backscattering spectrometry,” Vacuum, vol. 37 (5-6), pp. 429-432, May. 1987. DOI: http://doi.org/10.1016/0042-207X(87)90327-7.
[10] L. R. Doolittle, “Algorithms for the rapid simulation of Rutherford backscattering spectra,” Nucl. Instrum. Meth.B, vol. 9(1), pp. 344-351, Jun. 1985. DOI: http://doi.org/10.1016/0168-583X(85)90762-1.
[11] G. S. Frankel, J. R. Scully, and C. V. Jahnes, “Repassivation of Pits in Aluminum Thin Films,” J. Electrochem. Soc., vol. 143 (6), pp. 1834-1840, Jun. 1996. DOI: http://doi.org/10.1149/1.1836912.
[12] J. R. Galvele, “Transport processes in passivity breakdown—II. Full hydrolysis of the metal ions,” Corros. Sci., vol. 21 (8), pp. 551-579, Aug. 1981. DOI: http://doi.org/10.1016/0010-938X(81)90009-3.
[13] S. Garcia-Vergara, F. Colin, P. Skeldon, G. E. Thompson, P. Bailey, T. C. Q. Noakes, H. Habazaki, and K. Shimizu, “Effect of Copper Enrichment on the Electrochemical Potential of Binary Al-Cu Alloys,” J. Electrochem. Soc., vol. 151 (1), pp. B16-B21, Jan. 2004. DOI: http://doi.org/10.1149/1.1627343.
[14] A. Broli, and H. Holtan, “Use of potentiokinetic methods for the determination of characteristic potentials for pitting corrosion of aluminium in a deaerated solution of 3%NaCl,” Corros. Sci., vol. 13(4), pp. 237-246, Apr. 1973. DOI: http://doi.org/10.1016/0010-938X(73)90002-4.
[15] G. S. Frankel, “The growth of 2-D pits in thin film aluminium,” Corros. Sci., vol. 30 (12), pp. 1203-1218, Dec. 1990. DOI: http://doi.org/10.1016/0010-938X(90)90199-F.
[16] G. S. Frankel, M. A. Russak, C. V. Jahnes, M. Mirzamaani, and V. A. Brusic, “Pitting of Sputtered Aluminum Alloy Thin Films,” J. Electrochem. Soc., vol. 136(4), pp.1243-1244, Apr. 1989. DOI: http://doi.org/10.1149/1.2096864.
[17] X. Zhou, H. Habazaki, K. Shimizu, P. Skeldon, G. E. Thompson, and G. C. Wood, “Enrichment-dependent anodic oxidation of Zinc in Al-Zn Alloys,” Corros. Sci., vol. 38 (9), pp. 1563-1577, Sep. 1996.
[18] G. D. Davis, B. A. Shaw, B. J. Rees, and C. A. Pecile, “Electrochemical behavior and surface chemistry of non‐equilibrium aluminum–tantalum alloys: Solute‐rich interphase mechanisms,” Surf. Int. Anal., vol. 23 (9), pp. 609-617, Aug. 1995. DOI: http://doi.org/10.1002/sia.740230906.
[19] G. S. Frankel, R. C. Newman, C. V. Jahnes, and M. A. Russak, “On the Pitting Resistance of Sputter‐Deposited Aluminum Alloys,” J. Electrochem. Soc., vol. 140 (8), pp. 2192-2197, Aug. 1993. DOI: http://doi.org/10.1149/1.2220794.
[20] M. M. Lohrengel, “Thin anodic oxide layers on aluminium and other valve metals: high field regime,” Mat. Sci. Eng. R, vol. 11(6), pp. 243-294, Dec. 1993. DOI: http://doi.org/10.1016/0927-796X(93)90005-N.
[21] X. Zhou, C. Luo, T. Hashimoto, A.E. Hughes, and G.E. Thompson, “Study of localized corrosion in AA2024 aluminium alloy using electron tomography,” Corros. Sci., vol. 58, pp. 299-306, May. 2012. DOI: http://doi.org/10.1016/j.corsci.2012.02.001.
[22] X. Zhang, X. Zhou, T. Hashimoto, and B. Liu, “Localized corrosion in AA2024-T351 aluminium alloy: Transition from intergranular corrosion to crystallographic pitting,” Mat. Characterization, vol. 130, pp. 230-236, Aug. 2017. DOI: http://doi.org/10.1016/j.matchar.2017.06.022.
Downloads
Download data is not yet available.
