Optimización del efecto de la temperatura y altura del lecho en la bioadsorción de Cr (VI) en sistema continuo
Resumen
En el presente artículo se propone como adsorbentes residuos del proceso de extracción de almidón de plátano para remover Cr (VI) en un sistema continuo de lecho fijo, variando la temperatura 33, 40, 55, 70 y 76 °C y altura de lecho en el rango de 15.5, 30, 65, 100, 114.5 mm. El material adsorbente fue caracterizado mediante espectroscopia infrarroja por transformada de Fourier (FTIR), Microscopia Electrónica de Barrido (SEM) y análisis por difracción de rayos X (DRX). La solución de Cr (VI) a 100 ppm tuvo contacto con la columna por gravedad, con un caudal de 0.75 mL/s a las diferentes condiciones trabajadas. Al final del proceso la concentración residual del metal fue medida mediante espectroscopia UV-Vis usando el método estándar para la determinación de Cr (VI) en agua ASTM D1687-17. De los resultados, se estableció que el bioadsorbente cuenta con la presencia de grupos funcionales hidroxilo, carboxilo y metilo, y que el proceso de adsorción está controlado por interacciones electrostáticas; las variables evaluadas incidieron de forma significativa en el proceso, estableciendo al aplicar la metodología RSM que las condiciones óptimas de operación son 81.49 mm de altura de lecho y temperatura de 68 ºC. Del comportamiento de la curva de ruptura se encontró que el bio-material tiene potencial para ser usado como relleno en una columna de adsorción con el fin de remover Cr (VI).
Palabras clave
bioadsorción, biomasa residual, metal pesado, sistema continuo
Biografía del autor/a
Angel Villabona-Ortíz, M.Sc.
M.Sc. in Environmental Engineering, Universidad de Cartagena, Process Design and Biomass Utilization Research Group (IDAB), avillabonao@unicartagena.edu.co. ORCID: https://orcid.org/0000-0002-2323-1544
Erika Ruiz-Paternina
Master in Urban Sustainable Technologies, Universidad de Cartagena, Research Group on Process Design and Utilization of Biomasses (IDAB), Young COLCIENCIAS Researcher, erikbeatriz@gmail.com.
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