Determinación Espectrofotométrica Del Perfil Del Bisfenol A En El Proceso De Fotodegradación Con Oxígeno Molecular Singlete
DOI:
https://doi.org/10.19053/01217488.v11.n2.2020.11240Palabras clave:
quimiometría, PLS, robustez, cuantificación, espectrofotometría, fotosensibilizador, fotosensibilizaciónResumen
En este estudio se propuso evaluar una estrategia utilizando Partial Least Squares (PLS) como herramienta quimiométrica para establecer la robustez del proceso de degradación fotosensibilizada de Bisfenol A (BPA) en efluentes simulados. En esta la etapa del trabajo de investigación, se llevó a cabo la validación de la metodología que permitió la cuantificación de BPA mezclado con el fotosensibilizador Eosin Y (EOS) en solución acuosa. Utilizando la espectrofotometría como técnica de seguimiento, fue posible establecer el número óptimo de factores y el rango de longitud de onda, y determinar que es posible asegurar la cuantificación de BPA mediante PLS al demostrar la formación de complejos entre BPA y EOS. Los resultados de RMSE fueron 0,004237 a 284 nm y 0,009167 a 524 nm, lo que demuestra una buena solidez en el análisis. A continuación, se realizaron pruebas preliminares sobre el efecto de la luz directa utilizando una lámpara de mercurio como fuente de irradiación. En el caso del BPA se determinó que se alcanza el 100% de degradación a los 100 minutos. El fotosensibilizador se fotodegradó a los 50 minutos de exposición a la luz directa. La mezcla de los dos compuestos en el análisis preliminar podría demostrar un efecto de pantalla por parte del fotosensibilizador.
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Referencias
[1] C. a Staples, P. B. Dom, G. M. Klecka, T. O. Sandra, and L. R. Harris, “A review of the environmental fate, effects, and exposures of Bisphenol A,” Chemosphere, vol. 36, no. 10, pp. 2149–2173, 1998, doi: 10.1016/S0045-6535(97)10133-3.
[2] N. Bolong, a. F. Ismail, M. R. Salim, and T. Matsuura, “A review of the effects of emerging contaminants in wastewater and options for their removal,” Desalination, vol. 238, no. 1–3, pp. 229–246, 2009, doi: 10.1016/j.desal.2008.03.020.
[3] J. Gil, M. Soto, J. Usma, and O. Gutiérrez, “Contaminantes emergentes en aguas, efectos y posibles tratamientos,” Prod. Más Limpia, vol. 7, no. 2, pp. 52–73, 2012.
[4] L. N. Vandenberg, R. Hauser, M. Marcus, N. Olea, and W. V. Welshons, “Human exposure to bisphenol A (BPA),” Reproductive Toxicology, vol. 24, no. 2. pp. 139–177, 2007, doi: 10.1016/j.reprotox.2007.07.010.
[5] FDA, “‘Final report for the review of literature and data on BPA,’” 2014.
[6] EPA, “Bisphenol A (BPA) Action Plan,” 2010. [Online]. Available: https://www.epa.gov/assessing-and-managing-chemicals-under-tsca/bisphenol-bpa-action-plan.
[7] EPA, “Use of High Throughput Assays and Computational Tools in the Endocrine Disruptor Screening Program,” 2015. [Online]. Available: https://www.epa.gov/endocrine-disruption/use-high-throughput-assays-and-computational-tools-endocrine-disruptor#screening.
[8] EFSA, “Bisphenol A: new immune system evidence useful but limited,” 2016. [Online]. Available: http://www.efsa.europa.eu/en/press/news/161013.
[9] R. Andreozzi, “Advanced oxidation processes (AOP) for water purification and recovery,” Catal. Today, vol. 53, no. 1, pp. 51–59, 1999, doi: 10.1016/S0920-5861(99)00102-9.
[10] P. R. Gogate and A. B. Pandit, “A review of imperative technologies for wastewater treatment I: Oxidation technologies at ambient conditions,” Adv. Environ. Res., vol. 8, no. 3–4, pp. 501–551, 2004, doi: 10.1016/S1093-0191(03)00032-7.
[11] N. De la Cruz et al., “Degradation of emergent contaminants by UV, UV/H2O2 and neutral photo-Fenton at pilot scale in a domestic wastewater treatment plant,” Water Res., vol. 47, no. 15, pp. 5836–5845, 2013, doi: 10.1016/j.watres.2013.07.005.
[12] M. C. DeRosa and R. J. Crutchley, “Photosensitized singlet oxygen and its applications.pdf,” Coord. Chem. Rev., vol. 234, pp. 351–371, 2002.
[13] R. Bonnett, “Photosensitizers of the porphyrin and phthalocyanine series for photodynamic therapy,” Chem. Soc. Rev., vol. 24, no. 1, p. 19, 1995, doi: 10.1039/cs9952400019.
[14] F. Amat-Guerri, M. M. C. López-González, R. Martínez-Utrilla, and R. Sastre, “Singlet oxygen photogeneration by ionized and un-ionized derivatives of Rose Bengal and Eosin Y in diluted solutions,” J. Photochem. Photobiol. A Chem., vol. 53, no. 2, pp. 199–210, 1990, doi: 10.1016/1010-6030(90)87124-T.
[15] C. Bosch Ojeda and F. Sanchez Rojas, “Recent applications in derivative ultraviolet/visible absorption spectrophotometry: 2009-2011. A review,” Microchem. J., vol. 106, pp. 1–16, 2013, doi: 10.1016/j.microc.2012.05.012.
[16] D. Prato-Garcia and G. Buitrón, “Improvement of the robustness of solar photo-Fenton processes using chemometric techniques for the decolorization of azo dye mixtures,” J. Environ. Manage., vol. 131, pp. 66–73, 2013, doi: 10.1016/j.jenvman.2013.09.018.
[17] D. G. Kleinbaum, L. L. Kupper, K. E. Muller, and P. D. Press, Applied Regression Analysis and Other Multivariable Methods. 1978.
[18] N. Kumar, A. Bansal, G. S. Sarma, and R. K. Rawal, “Chemometrics tools used in analytical chemistry: An overview,” Talanta, vol. 123, pp. 186–199, 2014, doi: 10.1016/j.talanta.2014.02.003.
[19] H. Díaz, A. León, and G. Fraga, “Determinación esoectrofotometrica simultanea de la carbamazepina y fenobarbital en mezclas sinteticas utilizando la regresión por minimos cuadrados parciales,” Rev. Cuba. Química, vol. XX, no. 1, pp. 9–18, 2008.
[20] R. G. Brereton, “Introduction to multivariate calibration in analytical chemistry,” Analyst, vol. 125, no. 11, pp. 2125–2154, 2000, doi: 10.1039/b003805i.
[21] M. Grootveld, “Introduction to the Applications of Chemometric Techniques in ‘ Omics ’ Research : Common Pitfalls , Misconceptions and ‘ Rights and Wrongs ,’” in Metabolic profiling:disease and xenobiotics, no. 21, 2015, pp. 1–34.
[22] J. C. Vega- Vilca and Gúzman Jose, “Regresion PLS y PCA como solución al problema de multicolinealidad en regresión múltiple,” Rev. matemática Teor. y Apl., vol. 18, no. 1, pp. 9–20, 2011.
[23] A. Hoskuldsson, “A combined theory for PCA AND PLS,” J. Chemom., vol. 9, pp. 91–123, 1995.
[24] E. Díez-Mato, F. C. Cortezón-Tamarit, S. Bogialli, D. García-Fresnadillo, and M. D. Marazuela, “Phototransformation of model micropollutants in water samples by photocatalytic singlet oxygen production in heterogeneous medium,” Appl. Catal. B Environ., vol. 160–161, pp. 445–455, 2014.
[25] H. Benesi and J. H. Hildebrand, “A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic Hydrocarbons,” vol. 2832, no. 1948, 1949.
[26] PEN-RAY, “Penray lamps spectra,” Pen-ray lamps spectra, 2017.
[2] N. Bolong, a. F. Ismail, M. R. Salim, and T. Matsuura, “A review of the effects of emerging contaminants in wastewater and options for their removal,” Desalination, vol. 238, no. 1–3, pp. 229–246, 2009, doi: 10.1016/j.desal.2008.03.020.
[3] J. Gil, M. Soto, J. Usma, and O. Gutiérrez, “Contaminantes emergentes en aguas, efectos y posibles tratamientos,” Prod. Más Limpia, vol. 7, no. 2, pp. 52–73, 2012.
[4] L. N. Vandenberg, R. Hauser, M. Marcus, N. Olea, and W. V. Welshons, “Human exposure to bisphenol A (BPA),” Reproductive Toxicology, vol. 24, no. 2. pp. 139–177, 2007, doi: 10.1016/j.reprotox.2007.07.010.
[5] FDA, “‘Final report for the review of literature and data on BPA,’” 2014.
[6] EPA, “Bisphenol A (BPA) Action Plan,” 2010. [Online]. Available: https://www.epa.gov/assessing-and-managing-chemicals-under-tsca/bisphenol-bpa-action-plan.
[7] EPA, “Use of High Throughput Assays and Computational Tools in the Endocrine Disruptor Screening Program,” 2015. [Online]. Available: https://www.epa.gov/endocrine-disruption/use-high-throughput-assays-and-computational-tools-endocrine-disruptor#screening.
[8] EFSA, “Bisphenol A: new immune system evidence useful but limited,” 2016. [Online]. Available: http://www.efsa.europa.eu/en/press/news/161013.
[9] R. Andreozzi, “Advanced oxidation processes (AOP) for water purification and recovery,” Catal. Today, vol. 53, no. 1, pp. 51–59, 1999, doi: 10.1016/S0920-5861(99)00102-9.
[10] P. R. Gogate and A. B. Pandit, “A review of imperative technologies for wastewater treatment I: Oxidation technologies at ambient conditions,” Adv. Environ. Res., vol. 8, no. 3–4, pp. 501–551, 2004, doi: 10.1016/S1093-0191(03)00032-7.
[11] N. De la Cruz et al., “Degradation of emergent contaminants by UV, UV/H2O2 and neutral photo-Fenton at pilot scale in a domestic wastewater treatment plant,” Water Res., vol. 47, no. 15, pp. 5836–5845, 2013, doi: 10.1016/j.watres.2013.07.005.
[12] M. C. DeRosa and R. J. Crutchley, “Photosensitized singlet oxygen and its applications.pdf,” Coord. Chem. Rev., vol. 234, pp. 351–371, 2002.
[13] R. Bonnett, “Photosensitizers of the porphyrin and phthalocyanine series for photodynamic therapy,” Chem. Soc. Rev., vol. 24, no. 1, p. 19, 1995, doi: 10.1039/cs9952400019.
[14] F. Amat-Guerri, M. M. C. López-González, R. Martínez-Utrilla, and R. Sastre, “Singlet oxygen photogeneration by ionized and un-ionized derivatives of Rose Bengal and Eosin Y in diluted solutions,” J. Photochem. Photobiol. A Chem., vol. 53, no. 2, pp. 199–210, 1990, doi: 10.1016/1010-6030(90)87124-T.
[15] C. Bosch Ojeda and F. Sanchez Rojas, “Recent applications in derivative ultraviolet/visible absorption spectrophotometry: 2009-2011. A review,” Microchem. J., vol. 106, pp. 1–16, 2013, doi: 10.1016/j.microc.2012.05.012.
[16] D. Prato-Garcia and G. Buitrón, “Improvement of the robustness of solar photo-Fenton processes using chemometric techniques for the decolorization of azo dye mixtures,” J. Environ. Manage., vol. 131, pp. 66–73, 2013, doi: 10.1016/j.jenvman.2013.09.018.
[17] D. G. Kleinbaum, L. L. Kupper, K. E. Muller, and P. D. Press, Applied Regression Analysis and Other Multivariable Methods. 1978.
[18] N. Kumar, A. Bansal, G. S. Sarma, and R. K. Rawal, “Chemometrics tools used in analytical chemistry: An overview,” Talanta, vol. 123, pp. 186–199, 2014, doi: 10.1016/j.talanta.2014.02.003.
[19] H. Díaz, A. León, and G. Fraga, “Determinación esoectrofotometrica simultanea de la carbamazepina y fenobarbital en mezclas sinteticas utilizando la regresión por minimos cuadrados parciales,” Rev. Cuba. Química, vol. XX, no. 1, pp. 9–18, 2008.
[20] R. G. Brereton, “Introduction to multivariate calibration in analytical chemistry,” Analyst, vol. 125, no. 11, pp. 2125–2154, 2000, doi: 10.1039/b003805i.
[21] M. Grootveld, “Introduction to the Applications of Chemometric Techniques in ‘ Omics ’ Research : Common Pitfalls , Misconceptions and ‘ Rights and Wrongs ,’” in Metabolic profiling:disease and xenobiotics, no. 21, 2015, pp. 1–34.
[22] J. C. Vega- Vilca and Gúzman Jose, “Regresion PLS y PCA como solución al problema de multicolinealidad en regresión múltiple,” Rev. matemática Teor. y Apl., vol. 18, no. 1, pp. 9–20, 2011.
[23] A. Hoskuldsson, “A combined theory for PCA AND PLS,” J. Chemom., vol. 9, pp. 91–123, 1995.
[24] E. Díez-Mato, F. C. Cortezón-Tamarit, S. Bogialli, D. García-Fresnadillo, and M. D. Marazuela, “Phototransformation of model micropollutants in water samples by photocatalytic singlet oxygen production in heterogeneous medium,” Appl. Catal. B Environ., vol. 160–161, pp. 445–455, 2014.
[25] H. Benesi and J. H. Hildebrand, “A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic Hydrocarbons,” vol. 2832, no. 1948, 1949.
[26] PEN-RAY, “Penray lamps spectra,” Pen-ray lamps spectra, 2017.
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Publicado
2020-06-10
Cómo citar
Doria Herrera, G. M., Peñuela-Meza, G., Valencia, G. C., Gomez, I. N., & Soltan, J. (2020). Determinación Espectrofotométrica Del Perfil Del Bisfenol A En El Proceso De Fotodegradación Con Oxígeno Molecular Singlete. Ciencia En Desarrollo, 11(2), 177–190. https://doi.org/10.19053/01217488.v11.n2.2020.11240
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Artículos de investigación / Research papers
