Optimization of the Transesterification Process of Palm Oil using Ultrasound-based Technique
Abstract
This paper shows the results in the transesterification process on high oleic palm oil using the sonication –US- technique in combination with heterogeneous catalysts. The effect was evaluated separately from the US assistance and the catalyst (TiO2, CaO, MgCO3, Na2CO3 and K2CO3). Subsequently, the biodiesel obtained using the combination of US and catalysts was evaluated and optimal performances are achieved when using this combination, but it is Na2CO3 that provides the best results, generating a 71% conversion at 12h and in a 1:6 oil:alcohol ratio.
Keywords
Biodiesel, sonication, transesterification, heterogeneous catalysis
References
- J. Otera, “Transesterification,” Chem.Rev., vol. 93, pp. 1449–1470, 1993. DOI: https://doi.org/10.1021/cr00020a004
- E. F. Carreño Flórez, M. Y. Ferrer Pacheco, and G. Peña Rodríguez, “Zeolitas Sódicas y Potásicas a partir de Cenizas Volantes Provenientes de la Combustion del Carbón de la Termoeléctrica Termotasajero S.A.S,” Ciencia En Desarrollo, vol. 10, no. 2, 2019, doi: 10.19053/01217488.v10.n2.2019.8035. DOI: https://doi.org/10.19053/01217488.v10.n2.2019.8035
- A. enrique R. Sanabria, “Optimización del Proceso de Transesterificación de Aceite de Palma empleando la Técnica basada en Ultrasonido,” Universidad Nacional Abierta y a Distancia, 2018.
- W. W. S. Ho, H. K. Ng, and S. Gan, “Advances in ultrasound-assisted transesterification for biodiesel production,” Appl. Therm. Eng., vol. 100, pp. 553–563, 2016, doi: 10.1016/j.applthermaleng.2016.02.058. DOI: https://doi.org/10.1016/j.applthermaleng.2016.02.058
- M. . Ortiz, P. Garcia, L. M. Lagunes, M. I. Arregoitia, I. Garcia, and M. . León, “Obtencion de Biodisel a partir de aceite crudo de Palma (Elaeis guineensis jacq): Aplicación del método de ruta ascendente,” Acta Univ., vol. 26, no. 5, pp. 3–10, 2016. DOI: https://doi.org/10.15174/au.2016.910
- C. Stavarache, M. Vinatoru, R. Nishimura, and Y. Maeda, “Conversion of Vegetable Oil to Biodiesel Using Ultrasonic Irradiation,” Chem. Lett., vol. 32, no. 8, pp. 716–717, 2003, doi: 10.1246/cl.2003.716. DOI: https://doi.org/10.1246/cl.2003.716
- P. Mazo, L. Rios, and G. Restrepo, “Métodos Alternativos Para La Obtención De Biodiesel, Microondas Y Ultrasonido,” Revista ION, vol. 20, no. 1. pp. 51–57, 2007.
- I. Korkut and M. Bayramoglu, “Selection of catalyst and reaction conditions for ultrasound assisted biodiesel production from canola oil,” Renew. Energy, vol. 116, pp. 543–551, 2018, doi: 10.1016/j.renene.2017.10.010. DOI: https://doi.org/10.1016/j.renene.2017.10.010
- R. S. Malani, S. Patil, K. Roy, S. Chakma, A. Goyal, and V. S. Moholkar, “Mechanistic analysis of ultrasound-assisted biodiesel synthesis with Cu2O catalyst and mixed oil feedstock using continuous (packed bed) and batch (slurry) reactors,” Chem. Eng. Sci., vol. 170, pp. 743–755, 2017, doi: 10.1016/j.ces.2017.03.041. DOI: https://doi.org/10.1016/j.ces.2017.03.041
- M. Aghbashlo, M. Tabatabaei, S. Hosseinpour, Z. Khounani, and S. S. Hosseini, “Exergy-based sustainability analysis of a low power, high frequency piezo-based ultrasound reactor for rapid biodiesel production,” Energy Convers. Manag., vol. 148, pp. 759–769, 2017, doi: 10.1016/j.enconman.2017.06.038. DOI: https://doi.org/10.1016/j.enconman.2017.06.038
- M. R. Anuar and A. Z. Abdullah, “Ultrasound-assisted biodiesel production from waste cooking oil using hydrotalcite prepared by combustion method as catalyst,” Appl. Catal. A Gen., vol. 514, pp. 214–223, 2016, doi: 10.1016/j.apcata.2016.01.023. DOI: https://doi.org/10.1016/j.apcata.2016.01.023
- F. F. Pinheiro dos Santos, “Producción de Biodiesel asistida por ultrasonido,” Universidade Federal do Ceará, 2009.
- M. E. Fuentes-Campos, M. D. A. S., and S. T. G. G., “Ondas ultrasónicas aplicadas en el biodiésel producido con diferentes tipos de aceites vegetales,” Rev. del Inst. Investig. FIGMMG-UNMSM, vol. 19, no. 38, pp. 147–151, 2016.
- M. . Cano, “Evaluación de la producción de biodiesel a partir de aceite de moringa oleifera asistido por la técnica de ultrasonido,” Universidad Libre, 2015.
- D. R. Ortega, “Aceleración del proceso de transesterificación mediante una técnica basada en Ultrasonido,” Universidad del Cauca, 2016.
- Hielscher Ultrasound Technology, “Mezcla ultrasonica para la produccion de Biodiesel,” 2018. www.hielscher.com/es/bioisel.
- J. March, Advanced Organic Chemistry: Reactions, Mechanisms and Structure. John Wiley & Sons Inc., 1992.
- E. Farfan-Arribas and R. J. Madix, “Role of defects in the adsorption of aliphatic alcohols on the TiO2(110) surface,” J. Phys. Chem. B, vol. 106, no. 41, pp. 10680–10692, 2002, doi: 10.1021/jp020729p. DOI: https://doi.org/10.1021/jp020729p
- K. Tanabe and T. Yamaguchi, “Basicity and acidity of solid surfaces,” J. Res. Inst. Catal., pp. 179–184, 1963.
- U. Schuchardt, R. Sercheli, and R. Matheus, “Transesterification of Vegetable Oils : a Review General Aspects of Transesterification Transesterification of Vegetable Oils Acid-Catalyzed Processes Base-Catalyzed Processes,” J. Braz. Chem. Soc., vol. 9, no. 1, pp. 199–210, 1998, doi: 10.1590/S0103-50531998000300002. DOI: https://doi.org/10.1590/S0103-50531998000300002
- F. R. Siegel, “Chapter 9: Properties and Uses of Carbonates,” in Developments in Sedimentology, Elsevier, 1967. DOI: https://doi.org/10.1016/S0070-4571(08)71036-7
- V. Crespo, M. Martinez, and J. Aracil., “Biodiesel: Una alternative real al gasoleo mineral,” Ing. Quim., no. 377(3), pp. 135–145, 2001.
Downloads
Download data is not yet available.