Síntesis De Zβ A Partir de Cenizas Volantes, Utilizadas En Liberación Controlada De Nitratos

Autores/as

  • Jenny Andrea García Barrero Grupo de investigación Desarrollo y Aplicación de Nuevos Materiales - DANUM, Escuela de Ciencias Químicas, Facultad de Ciencias Básicas, Universidad Pedagógica y Tecnológica de Colombia
  • Mery Carolina Pazos Zarama Grupo de investigación Desarrollo y Aplicación de Nuevos Materiales - DANUM, Escuela de Ciencias Químicas, Facultad de Ciencias Básicas, Universidad Pedagógica y Tecnológica de Colombia
  • Javier Ramiro Chaparro Barajas Instituto de Ciencia de Los Materiales- España
  • Deisy Alejandra Fonseca Martínez Grupo de investigación Desarrollo y Aplicación de Nuevos Materiales - DANUM, Escuela de Ciencias Químicas, Facultad de Ciencias Básicas, Universidad Pedagógica y Tecnológica de Colombia
  • Esperanza Pavón González Instituto Ciencia de Materiales de Sevilla (CSIC-Universidad de Sevilla). Avda. Américo Vespucio, 49.41092 Sevilla, España
  • María Dolores Alba Carranza Instituto Ciencia de Materiales de Sevilla (CSIC-Universidad de Sevilla). Avda. Américo Vespucio, 49.41092 Sevilla, España

DOI:

https://doi.org/10.19053/01217488.v11.n2.2020.10748

Palabras clave:

adsorción, cenizas volantes, liberación controlada, nitratos, zeolita beta

Resumen

En este trabajo se sintetizó zeolita beta (Zβ) usando cenizas volantes (CV) de la central eléctrica de carbón, Termopaipa, situada en Paipa, Boyacá (Colombia). Las cenizas se utilizaron para extraer el silicio (Si) y aluminio (Al), para lo cual se realizó un pretratamiento ácido seguido de proceso hidrotérmico con NaOH.  Para la obtención de la zeolita beta se varió la fuente de silicio y aluminio del gel madre y el tiempo de cristalización, manteniendo una composición nominal igual a 50SiO2: 1Al2O3: 25TEAOH: Na2O: K2O: 17H2O. En el primer experimento, las CV aportaron la fuente de aluminio, mientras que la fuente de silicio se obtuvo a partir de las CV y sílice fumante. La síntesis hidrotérmica se realizó a 170 °C durante 40 h, lo cual condujo a la obtención de ZSM-5 junto con una fase secundaria de mordenita. En el segundo experimento, las CV aportaron la fuente de silicio y se requirió la adición de sulfato de aluminio octadecahidratado como fuente de aluminio. La síntesis hidrotérmica se realizó a 170 °C y 60 h, lo cual condujo a una Zβ de alta pureza. Las zeolitas se caracterizaron usando DRX, FTIR, SEM y XRF. Las zeolitas se modificaron usando (3-aminopropil) trietóxisilano (APTES) y bromuro de hexadeciltrimetilamonio (HDTMA-Br). Los resultados muestran que la Zβ-APTES, con una capacidad de adsorción de 5 mmol NO3-/100g tiene el mayor potencial para la aplicación de liberación controlada de fertilizantes.

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Publicado

2020-06-19

Cómo citar

García Barrero, J. A., Pazos Zarama, M. C., Chaparro Barajas, J. R., Fonseca Martínez, D. A., Pavón González, E., & Alba Carranza, M. D. (2020). Síntesis De Zβ A Partir de Cenizas Volantes, Utilizadas En Liberación Controlada De Nitratos. Ciencia En Desarrollo, 11(2), 159–175. https://doi.org/10.19053/01217488.v11.n2.2020.10748

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Artículos de investigación / Research papers

Métrica