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Generalized Additive Models to Optimize the Hydrophobicity Process of Kaolinite

Abstract

The wide industrial use of kaolinite requires that the extraction processes be modeled to determine the appropriate conditions of the benefit. Although classic linear regression models have been used, these have not been appropriate due to the non-compliance with normal distribution for the response variable. The data analyzed in this study correspond to a kaolinite extraction process by surface physicochemistry carried out in La Unión, Antioquia, Colombia. The response variable was the zeta potential and the explanatory variables were type of collecting solution, concentration, and pH. In this article, the recovery of kaolinite is modeled through generalized additive models, which can choose the statistical distribution and model all the parameters based on explanatory variables. Five distributions were selected for the response variable according to the Akaike information criterion ($AIC$). The model with generalized distribution Beta 2 was the model that presented the best performance according to the metrics used and it was found that the best-operating conditions obtained are the type of oleic acid collector, the concentration of 10 units, and pH 6

Keywords

additive models, hydrophobicity, kaolinite, regression models, zeta potential

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References

  • H. Akaike. A new look at the statistical model identification. IEEE transactions on automatic control, 19(6):716–723, 1974.
  • T. J. Cole and P. J. Green. Smoothing reference centile curves: The LMS method and penalized likelihood. Statistics in Medicine, 11(10):1305–1319, 1992. ISSN 02776715. doi: 10.1002/sim. 4780111005. URL https://onlinelibrary.wiley.com/doi/10.1002/sim.4780111005.
  • N. Elboughdiri, A. Mahjoubi, A. Shawabkeh, H. Khasawneh, and B. Jamoussi. Optimization of the degradation of hydroquinone, resorcinol and catechol using response surface methodology. Advances in Chemical Engineering and Science, 5:111–120, 2015. ISSN 0169-1317. doi: https://doi.org/10.4236/aces.2015.52012.
  • B. Ji and W. Zhang. Rare earth elements (rees) recovery and porous silica preparation from kaolinite. Powder Technology, 391:522–531, 2021. ISSN 0032-5910. doi: https://doi.org/10.1016/j.powtec.2021.06.028. URL https://www.sciencedirect.com/science/article/pii/S0032591021005520.
  • J. B. McDonald. Some generalized functions for the size distribution of income. Econometrica, 52(3):647–663, 1984. ISSN 00129682, 14680262. URL http://www.jstor.org/stable/1913469.
  • C. C. A. Melo, B. L. S. Melo, R. S. Angélica, and S. P. A. Paz. Gibbsite-kaolinite waste from bauxite beneficiation to obtain fau zeolite: Synthesis optimization using a factorial design of experiments and response surface methodology. Applied Clay Science, 170:125–134,
  • ISSN 0169-1317. doi: https://doi.org/10.1016/j.clay.2019.01.010. URL https://www.sciencedirect.com/science/article/pii/S0169131719300158.
  • N. J. Nagelkerke et al. A note on a general definition of the coefficient of determination. Biometrika, 78(3):691–692, 1991.
  • X. Qiu, X. Lei, A. Alshameri, H. Wang, and C. Yan. Comparison of the physicochemical properties and mineralogy of chinese (beihai) and brazilian kaolin. Ceramics International, 40(4):5397–5405, 2014. ISSN 0272-8842. doi: https://doi.org/10.1016/j.ceramint.2013.10.121. URL https://www.sciencedirect.com/science/article/pii/S027288421301393X.
  • R Core Team. R: A Language and Environment for Statistical Computing. R Foundation for Statistical Computing, Vienna, Austria, 2022. URL https://www.R-project. org/.
  • R. A. Rigby and D. M. Stasinopoulos. Mean and dispersion additive models. In W. Härdle and M. G. Schimek, editors, Statistical Theory and Computational Aspects of Smoothing, pages 215–230. Physica-Verlag Heidelberg, 1 edition, 1996. ISBN 978-3-7908-0930-5. doi:
  • 1007/978-3-642-48425-4.
  • R. A. Rigby and D. M. Stasinopoulos. A semi-parametric additive model for variance heterogeneity. Statistics and Computing, 6(1):57–65, mar 1996. ISSN 0960-3174. doi: 10.1007/BF00161574. URL http://link.springer.com/10.1007/BF00161574.
  • R. A. Rigby and D. M. Stasinopoulos. Generalized Additive Models for Location, Scale and Shape. Journal of the Royal Statistical Society. Series C (Applied Statistics), 54(3):507–554, 2005. URL http://www.jstor.org/stable/3592732.
  • R. A. Rigby and D. M. Stasinopoulos. Generalized additive models for location, scale and shape,(with discussion). Applied Statistics, 54:507–554, 2005.
  • M. Stasinopoulos, B. Rigby, and C. Akantziliotou. Instructions on how to use the gamlss package in r second edition, 2008.
  • L. Usuga-Manco, L.-V. A., and B.-R. M. Estudio de la hidrofobicidad de la caolinita de la Unión, Antioquia. Tecnológicas, 18:71–81, 2015.
  • D. Vadibeler, E. C. Ugwu, N. Martínez-Villegas, and B. Sen Gupta. Statistical analysis and optimisation of coagulation-flocculation process for recovery of kaolinite and calcium carbonate from suspensions using xanthan gum. Journal of Food, Agriculture and Envi-
  • ronment, 18(2):103–109, 2020. ISSN 1459-0263. doi: https://doi.org/10.1234/4.2020.5602. URL https://www.wflpublisher.com/Journal.
  • A. M. Zayed, A. Q. Selim, E. A. Mohamed, M. S. Abdel Wahed, M. K. Seliem, and M. Sillanp. Adsorption characteristics of na-a zeolites synthesized from egyptian kaolinite for manganese in aqueous solutions: Response surface modeling and optimization. Applied Clay Science, 140:17–24, 2017. ISSN 0169-1317. doi: https://doi.org/10.1016/j.clay.2017.01.027. URL https://www.sciencedirect.
  • com/science/article/pii/S0169131717300455.

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