Desarrollo de una aplicación para el cálculo de las propiedades de la mezcla amoniaco-agua
Resumen
El diseño y la optimización de sistemas energéticos en la actualidad son de gran importancia. Algunos de estos sistemas emplean la mezcla amoniaco-agua como fluido de trabajo, por lo tanto, el cálculo de las propiedades termodinámicas se vuelve indispensable para su evaluación, diseño y optimización. En el presente trabajo se ha desarrollado una aplicación en ExcelTM empleando Visual Basic (VBA) a partir de una formulación basada en la energía de Gibbs de exceso, con la finalidad de simular diversos sistemas, como pueden ser de refrigeración, aire acondicionado, bombas de calor, cogeneración y ciclos de potencia, sin la necesidad de adquirir simuladores comerciales para tal propósito. Para validar dicho programa se han comparado los resultados con los datos arrojados por el software desarrollado por el National Institute of Standars and Technology (NIST) y datos experimentales reportados en literatura.
Palabras clave
Mezcla amoniaco-agua, propiedades termodinámicas, energía libre de Gibbs de exceso, entalpía, entropía
Referencias
- A. Rivera, J. Cerezo, R. Rivero, J. Cervantes y R. Best, “Single Stage and Double Absorption heat transformers used to recover energy in a distillation column of butane and pentane”, Int J of Energy Research, vol. 27, pp. 1279-1292, 2003. doi: https:// doi.org/10.1002/er.943 DOI: https://doi.org/10.1002/er.943
- A.I. Kalina, “Combined cycle and waste-heat recovery power systems based on a novel thermodynamic energy cycle utilizing low-temperature heat for power generation”, ASME paper n.º 83-JPGC-GT-3, 1983. DOI: https://doi.org/10.1115/83-JPGC-GT-3
- S. Stecco y U. Desideri, “A thermodynamic analysis of the kalina cycles: comparisons, problems and perspectives”. Presentado en Gas Turbine and Aeroengine Congress and Exposition ASME, 1989. DOI: https://doi.org/10.1115/89-GT-149
- J. Hernández, C. Heard y R. Rivero, “Exergoeconomic comparison of a combined cycle cogeneration system with absorption refrigeration turbine inlet air cooling. Presentado en 16th International Conference on Efficiency, Costs, Optimization, Simulation and Environmental impact of energy systems. Copenhagen, Denmark, ECOS, 2003.
- R. Tillner-Roth y G. Friend, “Survey and Assesment of available measurements on thermodynamic properties of the mixture {Water+Ammonia}”, J Phys Chem Ref Data vol. 27, n.º 1, pp. 45-61, 1998. doi: https://doi.org/10.1063/1.556014 DOI: https://doi.org/10.1063/1.556014
- E. Thorin, “Thermophysical properties of ammonia-water mixtures for prediction of heat transfer areas in power cycles”, Int J Thermophys vol. 22, n.º 1, pp. 201-214, 2001. doi: https://doi.org/10.1023/A:1006745100278 DOI: https://doi.org/10.1023/A:1006745100278
- R.A. Macris, B.E. Eakin, R.T. Ellington y J. Huebler, “Physical and thermodynamic properties of ammonia-water mixtures” Research Bulletin Inst. of Gas Technology, n.º 14, 1964.
- R.T. Ellington, G. Kinst, R.E. Peck y J.F. Reed, “The absorption cooling process”, Research Bulletin Institute of Gas Technology, 1957.
- R. Tillner-Roth y G. Friend, “A Helmholtz free energy formulation of the thermodynamic properties of the mixture {Water+Ammonia}” J Phys Chem Ref Data, vol. 27, n.º 1, pp. 63-96, 1998. doi: https:// doi.org/10.1063/1.556015 DOI: https://doi.org/10.1063/1.556015
- S.H. Risvi y R.A. Heidemann, “Vapor-Liquid equilibria in the ammonia-water system”, J Chem Eng Data, vol. 32, 183-191, 1987. doi: https://doi. org/10.1021/je00048a017 DOI: https://doi.org/10.1021/je00048a017
- A. Vidal, R. Best, R. Rivero y J. Cervantes, “Analysis of a combined power and refrigeration cycle by the exergy method”, Energy, vol. 31, pp.
- , 2006. doi: https://doi.org/10.1016/j.energy.2006.03.001 DOI: https://doi.org/10.1016/j.energy.2006.03.001
- J. Pátek y J. Klomfar, “Simple functions for fast calculations of selected thermodynamic properties of the ammonia-water system”, Int J Refrig, vol. 18, n.º 4, pp. 228-234, 1995. doi: https://doi.org/10.1016/0140-7007(95)00006-W DOI: https://doi.org/10.1016/0140-7007(95)00006-W
- K. Sadhukhan, A.K. Chowdhuryi y B.K. Mandal, “Computer Based Thermodynamic Properties of Ammonia-Water Mixture for the Analysis of Power and Refrigeration Cycles”, International Journal of Thermodynamics, vol. 15, n.º 3, pp. 133-139, 2012. DOI: https://doi.org/10.5541/ijot.375 DOI: https://doi.org/10.5541/ijot.375
- E. Thorin, “Comparison of correlations for predicting thermodynamic properties of ammonia-water mixtures”, Int J Thermophys, vol. 21, n.º 4, pp. 853-870, 2000. doi: https://doi. org/10.1023/A:1006658107014 DOI: https://doi.org/10.1023/A:1006658107014
- E. Thorin, C. Dejfors, and G. Svedberg, “Thermodynamic properties of ammonia-water mixtures for power cycles”, Int J Thermophys, vol. 19, no. 2, pp. 501-510, 1998. https://doi. org/10.1023/A:1022525813769 DOI: https://doi.org/10.1023/A:1022525813769
- G.S. Alamdari, “Simple functions for predicting the thermodynamic properties of ammonia-water mixure”, IJE Transactions A: Basics vol. 20 n.º 1, pp. 95-104, 2007.
- G.S. Alamdari, “Simple equations for predicting entropy of ammonia-water mixure”. IJE Transactions B: Applications, vol. 20, n.º 1, 97-106, 2007.
- A.A. Zatorskii, “Algorithm for calculation of the parameters of the junction points of the cycles of absorption-type water-ammonia refrigeration machines in a digital computer”, Plenum Publishing Corporation, pp. 716-719, 1979. DOI: https://doi.org/10.1007/BF01155981
- K.E. Herold, K. Hain y M.J. Moran, “AMMWAT: A computer program for calculating the thermodynamic properties of ammonia and water mixtures using a Gibbs Free Energy formulation”, ASME vol. 4, pp. 65-75, 1988.
- Y.M. Park y R.E. Sonntag, “Thermodynamic properties of ammonia-water mixtures: a generalized equation-of-state approach”, ASME Trans, vol. 97, pp. 150-159, 1991.
- S.N. Mumah, S.S. Adefila y E.A. Arinze, “Properties generation procedures for first and second law analyses of ammonia-water heat pump system”, Energy Convers Mgmt, vol. 35, pp. 727736, 1994. doi:https://doi.org/10.1016/01968904(94)90058-2 DOI: https://doi.org/10.1016/0196-8904(94)90058-2
- A. Nowarski y D.G. Friend, “Application of the Extended Corresponding States Method to the Calculation of the Ammonia-Water Mixture Thermodynamic Surface”, International Journal of Thermophysics, vol. 19, pp. 1133-1142, 1998. doi: https://doi.org/10.1023/A:1022641709904 DOI: https://doi.org/10.1023/A:1022641709904
- R.M. Enick, G.P. Donahey y M. Holsinger, “Modeling the High-Pressure Ammonia-Water System with WATAM and the Peng-Robinson Equation of Sstate for Kalina Cycle Studies”, Ind Eng Chem Res, vol. 37, pp. 1644-1650, 1998. doi: https://doi. org/10.1021/ie970638s DOI: https://doi.org/10.1021/ie970638s
- L.A. Weber, “Estimating the virial coefficients of the ammonia + water mixture”, Fluid Phase Equilibria, vol. 162, pp. 31-49, 1999. doi: https://doi. org/10.1016/S0378-3812(99)00181-8 DOI: https://doi.org/10.1016/S0378-3812(99)00181-8
- F. Xu, y D.Y. Goswami, “Thermodynamic properties of ammonia-water mixtures for power-cycle applications”, Energy, vol. 24, pp. 525-536, 1999. doi: https://doi.org/10.1016/S0360-5442(99)00007-9 DOI: https://doi.org/10.1016/S0360-5442(99)00007-9
- R. Sharma, D. Singhal, R. Ghosh y A. Dwivedi, “Potential applications of artificial neural networks to thermodynamics: vapor–Liquid equilibrium predictions”, Computers and Chemical Engineering, vol. 23, pp. 385-390, 1999.doi:https://doi. org/10.1016/S0098-1354(98)00281-6 DOI: https://doi.org/10.1016/S0098-1354(98)00281-6
- R. Lugo, J. Guilpart y L. Fournaison, “Calculation method of thermophysical properties of ammo
- nia-water mixtures”, Presentado en Second Workshop on Ice Slurries, Paris France, International Institute of Refrigeration, 2000.
- A.A. Vasserman, A.G. Slynko, S.V. Bodyul, Yu.V. Gondarenko y E.S. Bodyul, “A Thermophysical Property Databank for Technically Important Gases and Liquids”, International Journal of Thermodynamics, vol. 22, pp. 477-485, 2001. doi: https:// doi.org/10.1023/A:1010774831521 DOI: https://doi.org/10.1023/A:1010774831521
- R. Lugo, L. Fournaison, J.M. Chourot y J. Guilpart, “An excess function method to model the thermophysical properties of one-phase secondary refrigerants”, International Journal of Refrigeration, vol. 25, pp. 916-923, 2002. doi: https://doi. org/10.1016/S0140-7007(01)00105-0 DOI: https://doi.org/10.1016/S0140-7007(01)00105-0
- R. Span y W. Wagner, “Equations of State for Technical Applications. I. Simultaneously Optimized Functional Forms for Nonpolar and Polar Fluids”, Int J of Thermophysics, vol. 24, pp. 1-39, 2003. doi: https://doi.org/10.1023/A:1022390430888 DOI: https://doi.org/10.1023/A:1022390430888
- R. Span y W. Wagner, “Equations of State for Technical Applications. III. Results for Polar Fluids”, Int J of Thermophysics, vol. 24, pp. 111-162, 2003, doi: https://doi.org/10.1023/A:1022362231796 DOI: https://doi.org/10.1023/A:1022362231796
- M. Barhoumi, A. Snoussi, E.N. Ben, K. Mejbri y A. Bellagi, “Modélistion des données thermodynamiques du mélange ammoniac/eau”, Int J Refrig, vol. 27, pp. 271-283, 2004. doi: https://doi. org/10.1016/j.ijrefrig.2003.09.005 DOI: https://doi.org/10.1016/j.ijrefrig.2003.09.005
- Kh. Mejbri y A. Bellagi, “Modelling of the thermodynamic properties of the water-ammonia mixture by three different approaches”. Int J Refrig, vol. 29, pp. 211-218, 2006. doi: https://doi.org/10.1016/j. ijrefrig.2005.06.002 DOI: https://doi.org/10.1016/j.ijrefrig.2005.06.002
- A. Sencan, “Artificial intelligent methods for thermodynamic evaluation of ammonia-water refrigeration system”, Energy Conv & Man, vol. 47, pp. 3319-3332, 2006. doi: https://doi.org/10.1016/j. enconman.2006.01.002 DOI: https://doi.org/10.1016/j.enconman.2006.01.002
- A.H. Farrokh-Niae, H. Moddarress y M. MohsenNia, “A three-parameter cubic equation of state for prediction of thermodynamic properties of fluids”. J Chem Thermodynamics, vol. 40, pp. 84-95, 2008. doi: https://doi.org/10.1016/j.jct.2007.05.012 DOI: https://doi.org/10.1016/j.jct.2007.05.012
- N.S. Ganesh y T. Srinivas, “Evaluation of thermodynamic properties of ammonia-water mixture up to 100 bar for power application systems”, Journal of Mechanical Engineering Research, vol. 3, no. 1, pp. 25-39, 2011.
- S. Kherris, M. Makhlouf, D. Zebbar y O. Sebbane, “Contribution study of the thermodynamics properties of the ammonia-water mixtures”, Thermal Science, vol. 17, n.º 3, pp. 891-902, 2013. doi: https://doi.org/10.2298/TSCI110206083K DOI: https://doi.org/10.2298/TSCI110206083K
- F. Li, L. Duanmu, L. Fu y X.L. Zhao, “Research and application of flue gas waste heat recovery in cogeneration based on absorption heat-exchange”, Procedia Engineering, vol. 146, pp. 594-603, 2016. doi: https://doi.org/10.1016/j.proeng.2016.06.407 DOI: https://doi.org/10.1016/j.proeng.2016.06.407
- A. Modi y F. Haglind, “A review of recent research on the use of zeotropic mixtures in power generation systems”, Energy Conversión and Management, vol. 138, pp. 603-626, 2017. doi: 10.1016/j. enconman.2017.02032 DOI: https://doi.org/10.1016/j.enconman.2017.02.032
- A. Rattner y S. Garimella, “Fast, stable computation of thermodynamic properties of ammonia-water mixtures”, International Journal of Refrigeration, 2015. doi: https://doi.org/10.1016/j. ijrefrig.2015.09.009
- M. Wang, A. Manera, S. Qiu y G.H. Su, “Ammonia-water mixture property code (AWProC) development, verification and Kalina cycle design for nuclear power plant”, Progress in Nuclear Energy vol. 91, pp. 26-37, 2016. DOI: 10.1016/j.pnucene.2016.04002 DOI: https://doi.org/10.1016/j.pnucene.2016.04.002
- O.M. Ibrahim y S.A. Klein, “Thermodynamic properties of ammonia-water mixtures”, ASHRAE Trans, pp. 1495-1502, 1993.
- Y.M. El-Sayed y M. Tribus, “Thermodynamic properties of water ammonia mixtures theoretical implementation for use in power cycles analysis”, Special publication AES New York, ASME, n.º 1, pp. 89-95, 1985.
- B. Ziegler y Ch. Trepp, “Equation of state for ammonia-water mixtures”, Int J Refrig, vol. 7, pp. 101-106, 1984. doi: https://doi.org/10.1016/01407007(84)90022-7 DOI: https://doi.org/10.1016/0140-7007(84)90022-7
- S.C Chapra y R.P. Canale, “Métodos numéricos para ingenieros”. Quinta Edición (Español), Mc Grau Hill Interamericana, México, 2007.
- P.C. Gillespie, W.V. Wilding y G.M. Wilson, “Vapor-Liquid equilibrium measurements on the ammonia-water system from 313 K to 589 K”. AIChE Symp Ser, vol. 83, n.º 256, pp. 97-127, 1987.
- J. Pospisil y Z. Fortelny, “Graphical expression of thermodynamic characteristics of absorption process in ammonia-water system”, EPJ Web of Conference, vol. 25, 01079(1)-01079(8), 2012. DOI:10.1051/eojconf/20122501079. DOI: https://doi.org/10.1051/epjconf/20122501079
- A. Sencan, S. Gök y E. Dikmen, “Prediction of liquid and Vapor Enthalpies of Ammonia-water Mixture”, Energy Source, Part A, vol. 33, pp. 1463-1473, 2011. doi:https://doi.org/10.1080/15567030903397891 DOI: https://doi.org/10.1080/15567030903397891
- K.H. Kim, K. Kim y H.J. Ko, “Entropy and exergy analysis of a heat recovery vapor generator for ammonia-water mixtures”, Entropy, vol. 16, pp. 20562070, 2014. DOI: 10.3390/e16042056 DOI: https://doi.org/10.3390/e16042056
- R.C.E. Campos, P.J.C. Escobar, S.C. Rodríguez, M. Leme, O.J. Venturini, L.E. Silva, C.V. Melián, D. dos S. Marques, D.F.R. Lofrano y V. Gialluca, “Exergetic and economic analysis of Kalina cycle foor low temperatura geotermal source in Brazil”, Presentado en Procedings of ECOS 2012. The 25th International conference on efficiency, cost, optimization, simulation and environmental impact of energy systems. Perugia, Italy, 2012.
- V. Srikanth, B.R. Narender y A. Gupta, “Thermodynamic Analysis of vapour absorption refrigeration system using solar energy”, International Journal of Latest Trends in Engineering and Thechnology, vol. 7, n.º 4, pp. 17-26, noviembre 2016. DOI: 10.21172/1.74003 DOI: https://doi.org/10.21172/1.74.003
- L. Becker y C.J.L. Corrales, “Fundamental EoS Implementation for {Water+ammonia} in Modelica”, Presentado en Proceedings of the 11th International Modelica Conference, September 21-23, pp. 647-652, 2015. doi: https://doi.org/10.3384/ ecp15118647
- M.A.I. El-Shaarawi, S.A.M. Said y M.U. Siddiqui, “New Correlation Equations for Ammonia-Water Vapor-Liquid Equilibrium (VLE) Thermodynamic Properties”, ASHRAE, DA-13-025, 2013.
- D. Kong, J. Liu, L. Zhang, H. He y Z. Fang, “Thermodynamic and Experimental Analysis of an Ammonia-Water Absorption Chiller”, Energy and Power Engineering, vol. 2, pp. 298-305, 2010. doi: https:// doi.org/10.4236/epe.2010.24042. DOI: https://doi.org/10.4236/epe.2010.24042
- L. Luo, H. Gao, Ch. Liu y X. Xu, “Parametric investigation and Thermoeconomic Optimization of a Combined Cycle for Recovering the Waste Heat From Nuclear Closed Brayton Cycle”, Science and Technology of Nuclear Installations, 2016. doi: https://doi.org/10.1155/2016/6790576 DOI: https://doi.org/10.1155/2016/6790576
- R. Rivero, G. Montero y R. Pulido, “Terminología para la Aplicación del Método de Exergia”, Revista del IMIQ, vol. 17, pp. 7-11, 1990.