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Vol. 15 Núm. 1 (2024)
Vol 15, Núm.1 (2024): Enero-Junio

Artículos de investigación / Research papers

Celulosa sulfonada como catalizador para la conversión eficiente de ácido levulínico en levulinato de etilo

https://doi.org/10.19053/01217488.v15.n1.2024.16871

Publicado 2024-02-13

  • Rodrigo Reynoso
    • ,
  • Gustavo A. Pasquale
    • ,
  • Diego M. Ruiz
    • ,
  • Luis A. Páez
    • ,
  • José J. Martinez
    • ,
  • Gustavo P. Romanelli

Rodrigo Reynoso
Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Centro de Investigaciónes en Sanidad Vegetal (CISaV)

Gustavo A. Pasquale
Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Centro de Investigaciónes en Sanidad Vegetal (CISaV

Diego M. Ruiz
Universidad Nacional de La Plata. Facultad de Ciencias Agrarias y Forestales. Centro de Investigaciónes en Sanidad Vegetal (CISaV)

Luis A. Páez
Fundación Universitaria Juan de Castellanos

José J. Martinez
Universidad Pedagógica y Tecnológica de Colombia UPTC

Gustavo P. Romanelli
Centro de Investigación en Ciencias Aplicadas “Jorge Ronco” (CINDECA). CONICET-Univesidad Nacional de La Plata

Resumen

Este estudio destaca el uso de ácido sulfúrico de celulosa como catalizador heterogéneo y reutilizable derivado de biomasa (Cortaderia Selloana) para sintetizar levulinato de etilo mediante esterificación catalítica de ácido levulínico con etanol. Se estudiaron los efectos de la temperatura, la carga del catalizador y la relación molar de etanol:ácido levulínico sobre el rendimiento de levulinato de etilo para optimizar la producción. Se logró un rendimiento del 95% a las 16 horas, 80 °C y una relación molar de 3:1 de etanol:ácido levulínico. Estos resultados demuestran que es factible obtener altos rendimientos de levulinato de etilo utilizando un catalizador derivado de biomasa.

Palabras clave

ácido sulfúrico de celulosa; levulinato de etilo; Esterificación del ácido levulínico

PDF

Citas

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