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Vol. 14 No. 1 (2023)
Vol 14, Núm.1 (2023): Enero-Junio

Artículos de investigación / Research papers

Evaluation of Glyphosate Adsorption Process in Aqueous Solutions on Fe(III) - Impregnated Bentonite and Kaolinite

https://doi.org/10.19053/01217488.v14.n1.2023.13806

Published 2023-03-02

  • yeyzon Javier cruz vera
    • ,
  • Ana María Montañez Velásquez
    • ,
  • Lisette Dyanna Ruiz Bravo
    • ,
  • Mery Carolina Pazos Zarama

yeyzon Javier cruz vera
Grupo de Investigación Desarrollo y Aplicación de Nuevos Materiales-DANUM, Escuela de Ciencias Químicas, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia-Uptc, Avenida Central del norte 39-115, Tunja, Boyacá, Colombia

Ana María Montañez Velásquez
Grupo de Investigación Desarrollo y Aplicación de Nuevos Materiales-DANUM, Escuela de Ciencias Químicas, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia-Uptc, Avenida Central del norte 39-115, Tunja, Boyacá, Colombia

Lisette Dyanna Ruiz Bravo
Grupo de Investigación en Materiales, Ambiente Y Desarrollo- MADE, Programa de Química, Facultad de Ciencias Básicas Universidad de la Amazonía, Calle 17 – diagonal 17 carrera 3F, Campus Porvenir, Florencia, Colombia

Mery Carolina Pazos Zarama
Grupo de Investigación Desarrollo y Aplicación de Nuevos Materiales-DANUM, Escuela de Ciencias Químicas, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia-Uptc, Avenida Central del norte 39-115, Tunja, Boyacá, Colombia

Abstract

Glyphosate is a widely used herbicide, however, its detection in water is an environmental problem due to its character as an emerging pollutant. The advanced oxidation processes - AOP are used for its degradation on materials modified with iron. In this study, the adsorption and catalytic degradation capacity of glyphosate was evaluated using bentonite and kaolinite impregnated with iron. The impregnated materials were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), and scanning electron microscopy (SEM), to determine structural changes, monitoring of incorporated iron content, and morphological changes, respectively. Subsequently, adsorption tests were carried out using aqueous glyphosate solutions in a concentration range between 12-27 mg/L of glyphosate, using UV-Vis spectroscopy for their quantification, the results showed that both bentonites and kaolinites impregnated with iron reached up to 55 % adsorption of the herbicide. Analysis by FT-IR showed that the impregnated bentonites after the adsorption process exhibit chemical interactions with the herbicide. The catalytic tests revealed that the materials used in this work and under the tested measurement conditions present a degradation percentage of up to 34%.

Keywords

Adsorption, Degradation, Glyphosate, Fe(III)-Impregnation

PDF (Español)

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