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Vol. 14 Núm. 1 (2023)
Vol 14, Núm.1 (2023): Enero-Junio

Artículos de investigación / Research papers

Evaluación de los procesos de adsorción del glifosato en disoluciones acuosas utilizando bentonita y caolinita impregnadas con Fe(III)

https://doi.org/10.19053/01217488.v14.n1.2023.13806

Publicado 2023-03-02

  • yeyzon Javier cruz vera
    • ,
  • Ana María Montañez Velásquez
    • ,
  • Lisette Dyanna Ruiz Bravo
    • ,
  • Mery Carolina Pazos Zarama

yeyzon Javier cruz vera
Grupo de Investigación Desarrollo y Aplicación de Nuevos Materiales-DANUM, Escuela de Ciencias Químicas, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia-Uptc, Avenida Central del norte 39-115, Tunja, Boyacá, Colombia

Ana María Montañez Velásquez
Grupo de Investigación Desarrollo y Aplicación de Nuevos Materiales-DANUM, Escuela de Ciencias Químicas, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia-Uptc, Avenida Central del norte 39-115, Tunja, Boyacá, Colombia

Lisette Dyanna Ruiz Bravo
Grupo de Investigación en Materiales, Ambiente Y Desarrollo- MADE, Programa de Química, Facultad de Ciencias Básicas Universidad de la Amazonía, Calle 17 – diagonal 17 carrera 3F, Campus Porvenir, Florencia, Colombia

Mery Carolina Pazos Zarama
Grupo de Investigación Desarrollo y Aplicación de Nuevos Materiales-DANUM, Escuela de Ciencias Químicas, Facultad de Ciencias, Universidad Pedagógica y Tecnológica de Colombia-Uptc, Avenida Central del norte 39-115, Tunja, Boyacá, Colombia

Resumen

El glifosato es un herbicida muy utilizado, sin embargo, su detección en agua es un problema ambiental debido a su carácter como contaminante emergente. Para su degradación se utilizan procesos de oxidación avanzada-POA sobre materiales modificados con hierro. En este estudio se evaluó la capacidad de adsorción y degradación catalítica del glifosato utilizando bentonita y caolinita impregnadas con hierro. Los materiales impregnados se caracterizaron mediante Difracción de Rayos X (DRX), Fluorescencia de Rayos X (FRX) y Microscopía Electrónica de Barrido (MEB), para determinar cambios estructurales, hacer un seguimiento al contenido de hierro incorporado y cambios morfológicos, respectivamente. Posteriormente, se realizaron pruebas de adsorción utilizando disoluciones acuosas de glifosato en un rango de concentraciones entre 12-27 mg/L de glifosato, utilizando espectroscopía UV-Vis para su cuantificación, los resultados demostraron que tanto las bentonitas como las caolinitas impregnadas con hierro alcanzaron hasta el 55% de adsorción del herbicida. El análisis por FT-IR demostró que las bentonitas impregnadas después del proceso de adsorción presentan interacciones químicas con el herbicida. Las pruebas catalíticas revelaron que los materiales utilizados en este trabajo y bajo las condiciones de medida probadas presentan un porcentaje de degradación de hasta el 34 %.

Palabras clave

Adsorción, Degradación, Glifosato, Impregnación con Fe(III)

PDF

Citas

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