Alúmina sulfonada: un catalizador adecuado para la valorización de componentes básicos de biomasa furfural a través de reacciones multicomponente.

Autores/as

  • Eliana Nope Departamento de Química, Facultad de Ciencias Exactas, Centro de Investigación y Desarrollo en Ciencias Aplicadas ‘‘Dr. J.J. Ronco’’ (CINDECA), UNLP-CCT CONICET-CIC. Calle 47 N8 257, B1900AJK La Plata, Argentina.
  • D. Ruiz Centro de Investigaciones en Sanidad Vegetal (CISaV), La Plata, Buenos Aires, Argentina
  • Angel Sathicq Departamento de Química, Facultad de Ciencias Exactas, Centro de Investigación y Desarrollo en Ciencias Aplicadas ‘‘Dr. J.J. Ronco’’ (CINDECA), UNLP-CCT CONICET-CIC. La Plata, Argentina.
  • Gustavo Romanelli Departamento de Química, Facultad de Ciencias Exactas, Centro de Investigación y Desarrollo en Ciencias Aplicadas ‘‘Dr. J.J. Ronco’’ (CINDECA), UNLP-CCT CONICET-CIC. La Plata, Argentina.

DOI:

https://doi.org/10.19053/01217488.v12.n1.2021.12821

Palabras clave:

valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes

Resumen

La alúmina sulfonada se sintetizó y ensayó por primera vez en la valorización del furfural mediante una reacción multicomponente para la preparación de un compuesto heterocíclico nitrogenado que contiene la subestructura de furano. Se obtuvieron diez heterociclos polisustituidos, pertenecientes a las dihidropirimidinonas (tiones) y 1,4-dihidropiridinas, con muy buenos rendimientos (70% - 85%) utilizando la metodología tándem y las condiciones de reacción verde. El catalizador se separó fácilmente del medio de reacción, dando un alto rendimiento en los estudios de reutilización. Se analizaron las métricas verdes para considerar la idoneidad de la reacción.

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Referencias

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Publicado

2021-05-10

Cómo citar

Nope, E., Ruiz, D., Sathicq, A., & Romanelli, G. (2021). Alúmina sulfonada: un catalizador adecuado para la valorización de componentes básicos de biomasa furfural a través de reacciones multicomponente. Ciencia En Desarrollo, 12(1), 113–123. https://doi.org/10.19053/01217488.v12.n1.2021.12821

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Artículos de investigación / Research papers

Métrica