Alúmina sulfonada: un catalizador adecuado para la valorización de componentes básicos de biomasa furfural a través de reacciones multicomponente.
Resumen
La alúmina sulfonada se sintetizó y ensayó por primera vez en la valorización del furfural mediante una reacción multicomponente para la preparación de un compuesto heterocíclico nitrogenado que contiene la subestructura de furano. Se obtuvieron diez heterociclos polisustituidos, pertenecientes a las dihidropirimidinonas (tiones) y 1,4-dihidropiridinas, con muy buenos rendimientos (70% - 85%) utilizando la metodología tándem y las condiciones de reacción verde. El catalizador se separó fácilmente del medio de reacción, dando un alto rendimiento en los estudios de reutilización. Se analizaron las métricas verdes para considerar la idoneidad de la reacción.
Palabras clave
valorización furfural, sílice sulfonada, reacción multicomponente, compuestos heterocíclicos nitrogenados, análisis de métricas verdes
Citas
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