Synthesis of an Anticorrosive Pigment by Thermal Treatment of Iron Oxides from Steel Industry Wastes
DOI:
https://doi.org/10.19053/01211129.v28.n52.2019.9653Keywords:
anticorrosive pigment, hematite, iron oxides, steel industry waste, thermal treatment, X ray diffractionAbstract
This work reports the obtaining of an anticorrosive pigment composed mainly of hematite (ɑ-Fe2O3) from a powder steel industry waste from rust scale of rebar steel. This residue is mainly composed of Fe2O3 (87.97 %), SiO2 (6.13 %), CaO (1.88 %), Al2O3 (1.30%) and MnO (0.77 %). The total iron oxide of the residue is constituted by the following crystalline phases: magnetite, maghemita, lepidocrocita, wüstite, goethite and hematite. The production of a pigment with a high content of hematite was possible thanks to the high content of precursor iron oxides, which were calcined at different temperatures (750-850 °C) and holding times (0.5-1.50 h). For characterizing the iron content chemically and to identify their iron oxides phases, it was used X-ray fluorescence (XRF) and X-ray diffraction (XRD). The results showed that the pigment with the highest amount of hematite (ɑ-Fe2O3) was obtained at a calcination temperature of 850 °C and a holding time of 1.00 h.
Downloads
References
[2] R. M. Cornell, and U. Shewertmann, “Transformations,” in The Iron Oxides, 2nd ed. Weinheim, Germany: Wiley-VCH, Jul. 2003, pp. 365-409. https://doi.org/10.1002/3527602097.ch14.
[3] R. Zboril, M. Mashlan, and D. Petridis, “Iron (III) Oxides from Thermal Processes Synthesis, Structural and Magnetic Properties, Mössbauer Spectroscopy Characterization, and Applications,” Chem. Mater., vol. 14 (3), pp. 969-982, Mar. 2002. https://doi.org/10.1021/cm0111074.
[4] O. R. K. Montedo, F. M. Bertan, R. Piccoli, D. Hotza, and A. P. N. de Oliveira, “Obtenção de Pigmentos de Óxido de Ferro a partir de Resíduos Siderúrgicos,” in Proc. 48th Annu. Meeting. of the Brazilian Ceramic Society, Curitiba, Brazil, 2004. Available at: https://www.ipen.br/biblioteca/cd/cbc/2004/artigos/48cbc-4-23.pdf.
[5] J. Balbuena, L. Sánchez, and M. Yusta-Cruz, “Use of Steel Industry Wastes for the Preparation of Self-Cleaning Mortars,” Materials, vol. 12 (4), pp. 1-13, Feb. 2019. https://doi.org/10.3390/ma12040621.
[6] R. Sugrañez, M. Yusta-Cruz, I. Marmol, J. Morales, and L. Sánchez, “Preparation of Sustainable Photocatalytic Materials through the Valorization of Industrial Wastes,” ChemSusChem, vol. 6 (12), pp. 2340-2347, Dec. 2013. https://doi.org/10.1002/cssc.201300449.
[7] S. Aguaiza, and O. Aldás, “Formación de hematita a partir de desechos sólidos producidos en la extracción de oro, mediante tratamientos térmicos,” Revista EPN, vol. 33 (2), 157-160, 2014.
[8] V. Della, J. A. Junkes, O. R. K. Montedo, A. P. N. Oliviera, C. R. Rambo, and D. Hotza, “Synthesis of Hematite from Steel Scrap to Produce Ceramic Pigments,” Am. Ceram. Soc. Bull., 86(5), 9101-1108, May. 2017.
[9] C. Sikalidis, T. Zorba, K. Chrissafis, and K. M. Paraskevopoulos, “Iron Oxide Pigmenting Powders Produced by Thermal Treatment of Iron Solid Wastes from Steel Mill Pickling Lines,” J. Therm. Anal. Calorim. vol. 86 (2), pp. 411-415, Nov. 2006. https://doi.org/10.1007/s10973-005-7168-8.
[10] H. Ovčačíková, “Possibilities of Recycling of Oiled Scale for Preparation of Pigments,” Acta Metall. Slovaca-Conf., vol. 14, pp. 90-97, Sep. 2014. https://doi.org/10.12776/amsc.v4i0.217.
[11] M. A. Legodi, and D. De Waal, “The Preparation of Magnetite, Goethite, Hematite and Maghemite of Pigment Quality from Mill Scale Iron Waste,” Dyes and Pigments. vol. 74 (1), pp. 161-168, Apr. 2007. https://doi.org/10.1016/j.dyepig.2006.01.038.
[12] E. Zitrou, J. Nikolaou, P. E. Tsakiridis, and G. D. Papadimitriou, “Atmospheric Corrosion of Steel Reinforcing Bars Produced by Various Manufacturing Processes,” Construction and Building Materials, vol. 21 (6), pp. 1161-1169, Jun. 2007. https://doi.org/10.1016/j.conbuildmat.2006.06.004.
[13] L. Cuesta, “Óxidos de hierro en pinturas anticorrosivas,” Inpra Latina, 19(1), pp. 26-30, Feb. 2014.
[14] H. S. A. Emira, N. A. Abdel-Khalek, and F. F. Abdel-Mohsen, “Protective Byproducts. Steelmaking Waste can be Converted to Anticorrosive Pigments,” Europ. Coatings Jnl., no. 10, pp. 40-46, Oct. 2007.
[15] E. Darezereshki, “Nano-Particles by Direct Thermal-Decomposition of Maghemita,” Materials Letters, vol. 65 (4), pp. 642-645, Feb. 2011. https://doi.org/10.1016/j.matlet.2010.11.030.
[16] K. Przepiera, and A. Przepiera, “Kinetics of Thermal Transformations of Precipitated Magnetite and Goethite,” J. Therm. Anal. Calorim., vol. 65 (2), pp. 497-503, Aug. 2001. https://doi.org/10.1023/A:1012441421955.
[17] Y. Cudennec, and A. Lecerf, “Topotactic Transformations of Goethite and Lepidocrocite into Hematite and Maghemita,” Solid State Sciences, vol. 7 (5), pp. 520-529, May. 2005. https://doi.org/10.1016/j.solidstatesciences.2005.02.002.
[18] K. Mori, T. Okada, Y. Takagi, Y. Takada, and T. Mizoguchi, “Oxidation and Disproportionation of Wüstite Studied by Mössbauer Spectroscopy,” Jpn. J. Appl. Phys., vol. 38 (2B), Feb.1999. https://doi.org/10.1143/JJAP.38.L189.
[19] A. M. Olmedo, “Estudio de películas de óxidos de hierro crecidas y depositadas en diversos ambientes,” Ph. D Disertation, Univ. Buenos Aires, Buenos Aires, Argentina, 1990. Available at: http://hdl.handle.net/20.500.12110/tesis_n2320_Olmedo.
[20] Y. M. Mos, A. C. Vermeulen, C. J. N. Buisman, and J. Weijma, “X-Ray Diffraction of Iron Containing Samples: The Importance of a Suitable Configuration,” Geomicrobiology Journal, vol. 35 (6), pp. 511-517, Jul. 2018. https://doi.org/10.1080/01490451.2017.1401183.
[21] P. Whitfield, “Laboratory X-Ray Powder Diffraction,” in U. Kolb, K. Shankland, L. Meshi, A. Avilov y W. David, Eds., Uniting Electron Crystallography and Powder Diffraction, Dordrecht, Países Bajos: Springer, 2012, pp. 53-65.
[22] A. C. Da Silva et al., “Converting Fe-rich Magnetic Wastes into Active Photocatalysts for Environmental Remediation Processes,” Journal of Photochemistry and Photobiology A Chemistry, vol. 335, pp. 259-267, Feb. 2017. https://doi.org/10.1016/j.jphotochem.2016.11.025.g.
[23] D. Jaramillo, “Desarrollo de un protocolo para la aplicación del método de Rietveld y del estándar interno en la caracterización de materiales cerámicos con contenido de amorfos,” Thesis, Univ. EAFIT, Medellín, Colombia, 2015. Available at: http://hdl.handle.net/10784/8531.
[24] M. Morcillo, and B. Chico, Eds. La corrosión atmosférica del acero al carbono en ambientes costeros, España: Editorial CSIC, 2018.
[25] J. Alcántara, D. De La Fuente, B. Chico, J. Simancas, I. Díaz, and M. Morcillo, “Marine Atmospheric Corrosion of Carbon Steel: A Review,” Materials, vol. 10 (4), pp. 1-67, Apr. 2017. https://doi.org/10.3390/ma10040406.
[26] S. Díaz, A. Forero, and O. J. Restrepo, “Hematita especular como pigmento natural en pinturas industriales,” Prospectiva, vol. 8 (1), pp. 71-76, Jun. 2010.
Downloads
Published
-
Abstract989
-
PDF (Español)869
-
PDF203
-
XML4
How to Cite
Issue
Section
License
All articles included in the Revista Facultad de Ingeniería are published under the Creative Commons (BY) license.
Authors must complete, sign, and submit the Review and Publication Authorization Form of the manuscript provided by the Journal; this form should contain all the originality and copyright information of the manuscript.
The authors who publish in this Journal accept the following conditions:
a. The authors retain the copyright and transfer the right of the first publication to the journal, with the work registered under the Creative Commons attribution license, which allows third parties to use what is published as long as they mention the authorship of the work and the first publication in this Journal.
b. Authors can make other independent and additional contractual agreements for the non-exclusive distribution of the version of the article published in this journal (eg, include it in an institutional repository or publish it in a book) provided they clearly indicate that the work It was first published in this Journal.
c. Authors are allowed and recommended to publish their work on the Internet (for example on institutional or personal pages) before and during the process.
review and publication, as it can lead to productive exchanges and a greater and faster dissemination of published work.
d. The Journal authorizes the total or partial reproduction of the content of the publication, as long as the source is cited, that is, the name of the Journal, name of the author (s), year, volume, publication number and pages of the article.
e. The ideas and statements issued by the authors are their responsibility and in no case bind the Journal.